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DUAN Chunjian, Cui Yu, WANG Chao, TAO Liming, WANG Qihua, Xie Hai, WANG Tingmei. High Temperature Tribological Properties of Thermosetting Polyimide[J]. TRIBOLOGY, 2017, 37(6): 717-724. DOI: 10.16078/j.tribology.2017.06.002
Citation: DUAN Chunjian, Cui Yu, WANG Chao, TAO Liming, WANG Qihua, Xie Hai, WANG Tingmei. High Temperature Tribological Properties of Thermosetting Polyimide[J]. TRIBOLOGY, 2017, 37(6): 717-724. DOI: 10.16078/j.tribology.2017.06.002

High Temperature Tribological Properties of Thermosetting Polyimide

Funds: The project was supported by the National Natural Science Foundation of China (U1630128) and the National Key Research and Development Plan (2016YFF0101000)
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  • Corresponding author:

    WANG Tingmei, E-mail: wangtin3088@sina.com, Tel: +86-931-4968252

  • Received Date: August 14, 2017
  • Revised Date: September 07, 2017
  • Accepted Date: September 27, 2017
  • Available Online: November 05, 2017
  • Published Date: November 27, 2017
  • Thermosetting polyimide oligomers with different diamines (isomers) was synthesized with 3,3’, 4,4’-biphenyltetracarboxylic dianhydride (s-BPDA), 4,4’-diaminodiphenyl ether (4,4’-ODA), 3,4’-diaminodiphenyl ether (3,4’-ODA) and 4-phenylethynylphthalide (4-PEPA). Furthermore, dry sliding tests were performed at 25 ℃, 100 ℃, 200 ℃, 250 ℃, 300 ℃ and 350 ℃ on a ball-on-disk wear tester. Mechanisms of friction and wear were studied in detail by scanning electron microscope and energy dispersive X-ray spectroscopy. At elevated temperature, experimental results demonstrated that the wear rate increased first, then decreased and finally increased. However, average coefficient of friction showed a tendency to plummet with temperature range from 25 ℃ to 350 ℃. This trend was attributed to changes in the mechanical properties of the polymer surface. The wear mechanisms at elevated temperatures were different. At 25 and 100 ℃, fatigue wear and abrasive wear prevailed. From 100 ℃ to 200 ℃, a dense of transfer film generated and the thickness increased due to adequate shearing motion of molecular chain. Hence, mild abrasive wear played a major role. Above 250 ℃, wear rate rapidly increased with damage of interaction between the molecular chain and polyimide was peeled on worn surface under the lasted load, adhesive wear was dominant. As a general guideline, higher ambient temperature rendered a greater wear rate.
  • [1]
    Zheng F, Lv M, Wang Q, et al. Effect of temperature on friction and wear behaviors of polyimide (PI)-based solid-liquid lubricating materials[J]. Polymers for Advanced Technologies, 2015, 26:988–993 doi: 10.1002/pat.v26.8
    [2]
    刘二勇, 贾均红, 高义民, 等.宽温域连续润滑材料的研究进展[J].中国表面工程, 2015, 28(4): 1–13 doi: 10.11933/j.issn.1007-9289.2015.04.001

    Liu Eryong, Jia Junhong, Gao Yimin, et al. Progress of continuous lubricating materials over a wide temperature range[J]. China Surface Engineering, 2015, 28(4):1–13(in Chinese) doi: 10.11933/j.issn.1007-9289.2015.04.001
    [3]
    陈建敏, 卢小伟, 李红轩, 等.宽温域固体自润滑涂/覆层材料的研究进展[J].摩擦学学报, 2014 , 34(5):592–600 doi: 10.16078/j.tribology.2014.05.016

    Chen Jianmin, Lu Xiaowei, Li Hongxuan et al. Progress of solid self-lubricating coating over a wide range of temperature[J]. Tribology, 2014 , 34(5):592–600(in Chinese) doi: 10.16078/j.tribology.2014.05.016
    [4]
    孙小波, 王枫, 葛世军, 等.航天长寿命轴承润滑技术[J].轴承, 2012(3): 60–64

    Sun Xiaobo, Wang Feng, Ge Shijun, et al. Long -life lubrication technology for bearing used in aerospace[J]. Tribology, 2012(3): 60–64(in Chinese)
    [5]
    Chose S, Cano R J, Britton S M, et al. Phenylethynyl Terminated Imide (PETI) Composites Made by High Temperature VARTM[J]. Chose Sayata, 2010
    [6]
    Harvey B G, Yandek G R, Lamb J T, et al. Synthesis and characterization of a high temperature thermosetting polyimide oligomer derived from a non-toxic, sustainable bisaniline[J]. RSC Advances, 2017, 37(7): 23149–23156
    [7]
    范琳, 陈建升, 胡爱军, 等.高性能聚酰亚胺材料的研究进展[J].材料工程, 2007(z1): 160–163 doi: 10.3969/j.issn.1001-4381.2007.z1.037

    Fan Lin, Chen Jiansheng, Hu Aijun, et al. Research development of polyaimde with high performance[J]. Materials Engineering, 2007(z1):160–163(in Chinese) doi: 10.3969/j.issn.1001-4381.2007.z1.037
    [8]
    Fang Q, Wang J, Gu S, et al. 3D porous crystalline polyimide covalent organic frameworks for drug delivery[J]. Journal of the American Chemical Society, 2015, 137(26): 8352–8355 doi: 10.1021/jacs.5b04147
    [9]
    Fusaro R L. Self-lubricating polymer composites and polymer transfer film lubrication for space applications[J]. Tribology International, 1990, 23(2): 105–122 doi: 10.1016/0301-679X(90)90043-O
    [10]
    Nie P, Min C, Song H J, et al. Preparation and Tribological Properties of Polyimide/Carboxyl-Functionalized Multi-walled Carbon Nanotube Nanocomposite Films Under Seawater Lubrication[J]. Tribology Letters, 2015, 58(1):7 doi: 10.1007/s11249-015-0476-7
    [11]
    Mu L, Shi Y, Feng X, et al. The effect of thermal conductivity and friction coefficient on the contact temperature of polyimide composites: experimental and finite element simulation[J]. Tribology International, 2012, 53: 45–52 doi: 10.1016/j.triboint.2012.04.003
    [12]
    Lv M, Zheng F, Wang Q, et al. Effect of proton irradiation on the friction and wear properties of polyimide[J]. Wear, 2014, 316(1): 30–36
    [13]
    Samyn P, Schoukens G. Tribological properties of PTFE‐filled thermoplastic polyimide at high load, velocity, and temperature[J]. Polymer Composites, 2009, 30(11): 1631–1646 doi: 10.1002/pc.v30:11
    [14]
    Zhao G, Hussainova I, Antonov M, et al. Friction and wear of fiber reinforced polyimide composites[J]. Wear, 2013, 301(1): 122–129
    [15]
    董凤霞, 侯国梁, 刘亮等.稀土改性对碳纤维增强聚酰亚胺复合材料在不同温度下摩擦学性能的影响[J].摩擦学学报, 2017, 37(2): 148–154 doi: 10.16078/j.tribology.2017.02.002

    Dong Fengxia, Hou Guoliang, Liu Liang, et al. Effect of surface treatment on carbon fibre by rare earth on the tribological properties of carbon fiber reinforced polyimide composite at elevated temperatures[J]. Tribology, 2017, 37(2): 148–154 (in Chinese) doi: 10.16078/j.tribology.2017.02.002
    [16]
    Gofman I V, Yudin V E, Orell O, et al. Influence of the degree of crystallinity on the mechanical and tribological properties of high-performance thermoplastics over a wide range of temperatures: from room temperature up to 250 ℃[J]. Journal of Macromolecular Science, Part B, 2013, 52(12): 1848–1860 doi: 10.1080/00222348.2013.808932
    [17]
    Yanming W, Tingmei W, Qihua W. Effect of molecular weight on tribological properties of thermosetting polyimide under high temperature[J]. Tribology International, 2014, 78: 47–59 doi: 10.1016/j.triboint.2014.04.031
    [18]
    Chen J, Jia J, Zhou H, et al. Tribological behavior of short‐fiber‐reinforced polyimide composites under dry‐sliding and water‐lubricated conditions[J]. Journal of Applied Polymer Science, 2008, 107(2): 788–796 doi: 10.1002/(ISSN)1097-4628
    [19]
    Chang K C, Lu H I, Peng C W, et al. Nanocasting technique to prepare lotus-leaf-like superhydrophobic electroactive polyimide as advanced anticorrosive coatings[J]. ACS Applied Materials & Interfaces, 2013, 5(4): 1460–1467
    [20]
    Zhang C, Su G, Chen H, et al. Synthesis of polyimides with low viscosity and good thermal properties via copolymerization[J]. Journal of Applied Polymer Science, 2015, 132(3)
    [21]
    Papadimitriou K D, Paloukis F, Neophytides S G, et al. Cross-linking of side chain unsaturated aromatic polyethers for high temperature polymer electrolyte membrane fuel cell applications[J]. Macromolecules, 2011, 44(12): 4942–4951 doi: 10.1021/ma200351z
    [22]
    Hergenrother P M, Connell J W, Smith J G. Phenylethynyl containing imide oligomers[J]. Polymer, 2000, 41(13): 5073–5081 doi: 10.1016/S0032-3861(99)00569-8
    [23]
    鲍登F P, 泰伯D. 固体的摩擦与润滑[M].北京:机械工业出版社, 1982

    Bowden F P, Talbot D. Friction and lubrication of solids[M]. Beijing: China Machine Press, 1982(in Chinese)
    [24]
    Li T, Tian J, Huang T, et al. Tribological behaviors of fluorinated polyimides at different temperatures[J]. Journal of Macromolecular Science, Part B, 2011, 50(5): 860–870 doi: 10.1080/00222348.2010.497023

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