ISSN   1004-0595

CN  62-1224/O4

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纳米LaF3微粒对聚酰亚胺粘结固体润滑涂层摩擦学性能及抗腐蚀性能的影响

Effect of Nanometer Lanthanum Fluoride as Filler on the Tribological Behavior and Corrosion Resistance of Polyimide Boned Solid Lubricating Coating

  • 摘要: 采用MHK-500型摩擦磨损试验机考察了含纳米LaFa微粒的聚酰亚胺粘结固体润滑涂层在干摩擦条件下同GCr15钢环配副时的摩擦学性能,评价了涂层的耐腐蚀性能,重点探讨了纳米LaFa填料对涂层耐磨性及耐腐蚀性能的影响.结果表明:含1%~2%纳米LaF3的涂层的耐磨性最佳,而纳米LaF3填料对涂层减摩性能的影响不大;含2%纳米LaF3的涂层的耐腐蚀性最好.

     

    Abstract: The tribological behavior of polyimide (PI) boned solid lubricating coatings filled with nanometer lanthanum fluoride (LaF_3) sliding against SAE2100 steel was examined on an MHK-500 friction and wear tester, using the PI-based coating without nano-LaF_3 as a control. The corrosion resistance of the coatings was evaluated according to GB 10125-88. Thus the effect of nano-LaF_3 as the filler on the antiwear ability and corrosion resistance of the coatings was highlighted. It was found that the coating with l%~2% nano-LaF_3 showed the best antiwear ability, but it recorded a friction coefficient almost the same as that of the coating without the nano-LaF_3 filler. Moreover, the incorporation of 2% nano-LaF_3 filler led to a significant increase in the corrosion resistance of the coating, and the corrosion resistance of the PI-based bonded solid lubricating coatings were related to the water contact angles. Namely, the PI-based coating containing 4% nano-LaF_3 had a smaller water contact angle, which corresponded to the poorer corrosion resistance of the coating. The improvement in the wear resistance and corrosion resistance of the PI-based bonded solid lubricating coatings by the incorporation of the nano-LaF_3 filler was attributed to the strengthened interfacial bonding among the nano filler and the polymeric matrix and various other fillers. However, the PI-based coating of a too high mass fraction of the nano filler had increased surface and interface defects, which led to the worsening of the wear resistance and corrosion resistance of the coating.

     

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