Tribological Characteristics of Fe-Mo-Ni-Cu-Graphite High Temperature Self-Lubricating Composites
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摘要: 采用粉末冶金工艺,在Fe-Mo-石墨自润滑复合材料的基础上,制备了添加Ni、Cu两种元素的Fe-Mo-Ni-Cu-石墨高温自润滑复合材料,并在栓-盘式高温摩擦试验机上考察了其在室温、320和450 ℃下的摩擦学性能;采用金相显微镜、XRD和SEM等表征方法,分析了材料金相组织、物相成分和摩擦表面形貌.结果表明:Fe-Mo-石墨自润滑复合材料中添加Ni和Cu元素,可以强化基体,增强材料的力学性能,改善材料的摩擦学性能.在高温摩擦过程中,Fe-Mo-Ni-Cu-石墨高温自润滑复合材料摩擦表面生成的由石墨+CuFe5O8 +Fe3O4+Fe2.6Ni0.4O4组成的复合润滑膜是导致其具有良好高温润滑性的主要原因.
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关键词:
- Fe基自润滑复合材料 /
- 高温 /
- 摩擦磨损 /
- 氧化物复合润滑膜
Abstract: Fe-Mo-Ni-Cu-graphite high temperature self-lubricating composites which were derived from Fe-Mo-graphite self-lubricating composites were fabricated by powder metallurgy technology. Tribological properties were investigated on a high temperature tribometer with a pin-on-disc configuration at room temperature, 320 ℃ and 450 ℃. Metallography microscopy, scanning electron microscopy and X-ray diffraction were utilized to characterize the microstructure, morphologies and phase composition of the composite. Experimental results show that the addition of Ni and Cu strengthened the matrix, enhanced mechanical properties, and improved the tribological properties of materials. The black composite lubricating film on the worn surface of Fe-Mo-Ni-Cu-graphite high temperature self-lubricating composites was responsible for the good tribological property at elevated temperature. -
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[1] 薛群基,吕晋军.高温固体润滑研究的现状及发展趋势[J].摩擦学学报,1999,19(1): 91-96. Xue Q J,Lu J J. Research status and developing trend of solid lubrication at high temperatures[J]. Tribology,1999,19(1): 91-96.
[2] E P Georgious,S Achanta,S Dosta,et al. Structural and tribological properties of supersonic sprayed Fe-Cu-Al-Al2O3 nanostructured cermets[J]. Applied Surface Science,2013,275: 142-147.
[3] C Ferrer,M Pascual,D Busquets,et al. Tribological study of Fe-Cu-Cr-graphite alloy and cast iron railway brake shoes by pin-on-disc technique[J]. Wear,2010,268: 784-789.
[4] Kang Y H,Yang J. Dry-sliding tribological behavior of Fe-Ni alloys[J]. Tribology International,2012,51: 11-17.
[5] 韩杰胜,刘维民,吕晋军,等. Fe-Mo-(MoS2/PbO)高温自润滑材料的摩擦学特性[J]. 摩擦学学报,2008,26(1):118-120. Han J S,Liu W M,Lu J J,et al. Tribological properties of Fe-Mo-(MoS2/PbO) high temperature self-lubricating material[J]. Tribology,2008,26(1): 118-120.
[6] 韩杰胜,王静波,张树伟,等. Fe-Mo-CaF2高温自润滑材料的摩擦学特性研究[J]. 摩擦学学报,2003,23(4):306-310. Han J S,Wang J B,Zhang S W,et al. Study on the tribological properties of Fe-Mo-CaF2 high temperature self-lubricating material[J]. Tribology,2003,23(4): 306-310.
[7] 丁光玉,冯辉霞,任卫,等.添加镍包覆石墨对铁基固体自润滑复合材料性能的影响[J].粉末冶金技术,2009,27(9): 11-19. Ding G Y,Feng H X,Ren W,et al. Effect of the Ni coated graphite powders addition on the properties of the Fe-based solid self-lubricating composites[J]. Powder Metallurgy Technology,2009,27(1):11-14.
[8] 郭鸿儒,陆龙,王静波. Mo含量对 Fe-石墨材料高温摩擦学特性的影响[J].甘肃科技,2012,41(1): 33-34. Guo H R,Lu L,Wang J B. Effect of the content of molybdenum on tribological properties of Fe-graphite materials[J]. Gansu Science and Technology,2012,41(1): 33-34.
[9] 马文林,陆龙,郭鸿儒,等.Fe-Mo-石墨和Fe-Mo-Ni-石墨的高温摩擦磨损行为[J].摩擦学学报,2013,33(5):475-479. Ma W L,Lu L,Guo H R,et al. Tribological behavior of Fe-Mo-Graphite and Fe-Mo-Ni-Graphite composites at elevated temperature[J]. Tribology,2013,33(5): 475-479.
[10] 艾星辉.金属学[M]. 北京,冶金工业出版社,2009:199-200. Ai X H. Metal science[M]. Beijing: Metallurgical Industry Press,2009:199-200 .
[11] Peterson M B,Calabrese S J,Li S Z,et al. Paper I (II) frictional properties of lubricating oxide coatings[J]. Tribology Series,1990,17: 15-25.
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