ISSN   1004-0595

CN  62-1224/O4

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石墨对三氧化二铝/铜金属陶瓷复合材料摩擦磨损性能的影响

Study of Graphite Action in Al2O3-Cu Matrix

  • 摘要: 采用粉末冶金技术制备了Al2O3/Cu石墨复合材料;采用MM-200型摩擦磨损试验机考察了石墨对Al2O3/Cu基金属陶瓷复合材料摩擦磨损性能和硬度的影响;采用扫描电子显微镜分析了复合材料磨损表面形貌.结果表明:Al2O3/Cu基复合材料的摩擦系数随石墨含量的增加而降低,当石墨含量大于1.0%后,摩擦系数降低明显;当石墨含量低于3%时,Al2O3/Cu基复合材料的磨损体积损失随石墨含量的增加而降低;当石墨含量低于2.0%时,石墨对Al2O3/Cu基复合材料的硬度无明显影响;当石墨含量超过3.0%后,Al2O3/Cu基复合材料的硬度随石墨含量的增加迅速降低;此外,石墨使得Al2O3/Cu基复合材料磨损表面的微裂纹减少、裂纹长度缩短;当石墨含量达到2.5%时,复合材料磨损表面微裂纹消失.这是由于石墨在磨损表面形成固体润滑膜,从而降低摩擦力并减少裂纹源所致.

     

    Abstract: Al_2O_3-Cu matrix composites doped with graphite of various mass fractions were prepared using powder metallurgy. The influence of graphite on the hardness and tribological behavior of the Al_2O_3-Cu cermet composite was investigated. The worn surface morphologies of the cermet composites were observed using a scanning electron microscope. Thus the friction and wear behaviors of the cermet composites sliding against 40Cr steel in a ring-on-block configuration and under discontinuous lubricated condition were evaluated on an MM-200 test rig. It was found that the incorporation of the graphite at a proper mass fraction contributed to effectively decrease the friction coefficients and wear volume losses of the cermet composites, which was attributed to the self-lubricity of the graphite lubricating film formed on the worn composite surface. At the same time, the lubricating film of the graphite also contributed to restrain the initiation of micro cracks on the worn surface of the cermet composite. It was imperative to keep the mass fraction of the graphite in the cermet composite as 3.0% so as to obtain the optimized mechanical and tribological properties of the composites. Otherwise, the hardness and wear-resistance of the cermet composites would be significantly worsened in the presence of excessive graphite as the filler. In other words, too high content of graphite was harmful to the bonding strength between the metallic matrix and the reinforcing ceramic particulates, which hence led to a significant damage to the mechanical strength and wear-resistance of the cermet composite, even though the graphite could function to reduce the friction to some extent.

     

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