ISSN   1004-0595

CN  62-1224/O4

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激光相变硬化与时效处理对17-4PH钢微观组织与汽蚀行为的影响研究

Influence of Laser Phase Transformation Hardening and Aging Treatment on the Microstructure and Cavitation Erosion Behavior of 17-4PH Steel

  • 摘要: 汽轮机末级叶片在服役过程中,进气边常面临汽蚀破坏的风险,从而导致叶片尺寸缺失,对机组的整体运行产生不良影响. 激光相变硬化在提升材料强度、耐磨性及抗疲劳性能方面具有巨大潜力,在激光相变硬化的基础上进行时效处理可进一步提升材料的力学性能,但目前关于激光相变硬化时效处理对汽轮机叶片17-4PH钢的抗汽蚀性能的影响研究较少. 因此,本文中以17-4PH钢为材料,研究激光相变硬化、激光相变硬化时效处理和传统固溶时效处理3种处理工艺下17-4PH钢微观组织分布、硬度关系、抗汽蚀性能与汽蚀损伤机理. 结果表明:激光相变硬化后形成了以粗大板条马氏体为主的一次硬化区和回火马氏体为主的二次硬化区,一次硬化区表面平均硬度为352 HV0.5,较基体提升12.8%,二次硬化区表面平均硬度为381 HV0.5,较基体提升22.1%. 激光相变硬化经时效处理后,组织均匀性提升,形成明显的板条马氏体结构,表面平均硬度达451 HV0.5. 传统固溶时效处理的组织以板条马氏体和铁素体为主,表面平均硬度为410 HV0.5. 与传统固溶时效试样和激光相变硬化试样相比,激光相变硬化时效试样有明显的ε-Cu和奥氏体的衍射峰. 激光相变硬化时效处理试样的累积质量损失最低,仅为60.28 mg,相较未处理试样、激光相变硬化试样和传统固溶时效试样分别减少了55.1%、31.8%和10.5%. 各试样在汽蚀过程中,材料的损失机理均为裂纹扩展导致的剥落;但经时效处理后,析出的ε-Cu增加了位错运动阻力,限制了裂纹向内部扩展,激光相变硬化时效试样表面损伤较小、质量损失最小.

     

    Abstract: During the service process of the last-stage blades of a steam turbine, the inlet edges often face the risk of cavitation damage, which leads to the loss of blade dimensions and has an adverse impact on the overall operation of the unit. Laser phase transformation hardening has great potential in improving the strength, wear resistance and fatigue resistance of materials. Aging treatment based on laser phase transformation hardening can further enhance the mechanical properties of materials. However, currently, there are few studies on the influence of laser phase transformation hardening and aging treatment on the cavitation-erosion resistance of 17-4PH steel used in steam turbine blades. Therefore, in this paper, taking 17-4PH steel as the material, the microscopic tissue distribution, hardness relationship, cavitation resistance and cavitation damage mechanism of 17-4PH steel under three treatment processes, namely laser phase transformation hardening, laser phase transformation hardening and aging treatment, and traditional solution aging treatment were studied. The results showed that after laser phase transformation hardening, a primary hardened zone mainly composed of coarse lath martensite and a secondary hardened zone mainly composed of tempered martensite were formed. The average surface hardness of the primary hardened zone was 352 HV0.5, which was 12.8% higher than that of the matrix, and the average surface hardness of the secondary hardened zone was 381 HV0.5, which was 22.1% higher than that of the matrix. After aging treatment of laser phase transformation hardening, the uniformity of the microstructure was improved, an obvious lath martensite structure was formed, and the average surface hardness reached 451 HV0.5. The structure of the traditional solution aging treatment was mainly composed of lath martensite and ferrite, and the average surface hardness was 410 HV0.5. Compared with the traditional solution aging and laser phase transformation hardening samples, the laser phase transformation hardening and aging sample had obvious diffraction peaks of ε-Cu and austenite. The cumulative mass loss of the sample treated by laser phase transformation hardening and aging was the lowest, only 60.28 mg, which was 55.1%, 31.8% and 10.5% less than that of the untreated sample, the laser phase transformation hardening sample and the traditional solution aging sample respectively. During the cavitation process of each sample, the material loss mechanism was spalling caused by crack propagation. However, after aging treatment, the precipitated ε-Cu increased the resistance to dislocation movement and restricted the crack from propagating inward. As a result, the surface damage of the laser phase transformation hardening and aging sample was relatively small, and the mass loss was the minimum.

     

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