ISSN   1004-0595

CN  62-1224/O4

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磷酸盐复合涂层与不同材料配副的宽温域摩擦学行为研究

Tribological Behaviors of Phosphate Composite Coatings under different Formulations in a Wide Temperature Range

  • 摘要: 为了满足新型机械装备对宽温域粘结固体润滑防护涂层材料服役寿命要求的提升,本文中设计制备了具有宽温域润滑性能的无机磷酸盐粘结固体润滑涂层材料,并系统研究了所制备涂层材料在不同摩擦副下的宽温域摩擦学行为与磨损机制. 研究结果表明:所制备无机磷酸盐粘结固体润滑涂层在25~600 ℃温度范围内具有良好的摩擦学性能,其平均摩擦系数在0.25以下. 同时,当涂层与不同摩擦副对摩时,室温下涂层的摩擦系数变化差异不大,在0.16至0.18范围内;200和400 ℃时,涂层与表面镀Cr2O3小球(GCr2O3球)对摩时的摩擦学性能表现最佳,其平均摩擦系数低于0.1,这主要是由于Cr2O3膜本身具有良好的高温润滑性能. 600 ℃时,涂层中MoS2和石墨等润滑填料在高温氧化与摩擦剪切力的共同耦合作用下短期内氧化失效,由原位形成的钼酸盐类新物相发挥高温润滑作用,导致在不同摩擦副下复合涂层的摩擦系数变化趋势相似,磨损率增大至10−4 mm3/(N·m)量级.

     

    Abstract: Against the background of the rapid changes in contemporary engineering science and technology, technological innovations in new machinery and equipment face unprecedented challenges in terms of the performance of key components. Mechanical equipment possesses the advantages about high efficiency, stability, and long-life operation, the wide temperature range bonded solid lubrication protective coatings are one of the important key of which, in the context of scientific research and engineering, the enhancement of the service life of such materials represents a crucial challenge that must be urgently addressed. This paper fully took into account the unique chemical structure and bonding characteristics of inorganic phosphates, precisely regulated the proportional relationship between them and other functional components, designed and prepared inorganic phosphate bonded solid lubrication coating materials with wide-temperature-range lubrication performance, and systematically studied the wide-temperature-range tribological behaviors and wear mechanisms of the prepared coating materials under different friction pairs. The research results showed that the prepared inorganic phosphate bonded solid lubrication coating had good tribological properties within the temperature range of 25 ℃ to 600 ℃, and its average friction coefficient was below 0.25. Meanwhile, when the coating was rubbed against different friction pairs, the variation in the friction coefficient of the coating at room temperature was not significant, ranging from 0.16 to 0.18. Through the analysis of the microscopic wear morphology, its main wear mechanism was abrasive wear. At 200 ℃ and 400 ℃, the tribological performance of the coating when rubbed against the surface-plated Cr2O3 small balls (GCr2O3 balls) was the best, with its average friction coefficient being lower than 0.1, which was mainly due to the good high-temperature lubrication performance of the Cr2O3 film itself. At 600 ℃, the lubricating fillers such as MoS2 and graphite in the coating were oxidized and failed in a short period under the combined coupling effect of high-temperature oxidation and frictional shear force, and the newly formed molybdate phases in situ played a role in high-temperature lubrication. Under the coupling effect of high temperature and frictional shear force, the surface plating on the counterpart surface was worn out in a short period, and the difference in the influence of the counterpart material on the tribological performance of the coating could be almost ignored, resulting in similar variation trends of the friction coefficient of the composite coating under different friction pairs and an increase in the wear rate to the order of 10−4 mm3/(N·m). At this time, the wear mechanism was mainly abrasive, adhesive, and fatigue wear under the combined action of high-temperature oxidation and frictional shear force. It was worth noting that in a high-temperature environment, the Ag element showed a tendency to migrate more easily to the surface of the Cr2O3 film layer.

     

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