ISSN   1004-0595

CN  62-1224/O4

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电化学极化密封CrN涂层孔隙及对摩擦学性能的影响

Sealing Effect of Electrochemical Polarization and Its Influence on the Tribological Properties of CrN Coatings

  • 摘要: 为密封CrN涂层中的孔隙缺陷,从而提高其力学及摩擦学性能,本文中对CrN涂层进行不同扫描速率的电化学极化(EP)处理,研究扫描速率对CrN涂层的微观结构、力学性能以及摩擦学性能的影响. 研究结果发现:EP处理后CrN涂层仍然保持稳定的CrN (111)的晶体结构,在X射线衍射(XRD)图谱中未发现氧化铬衍射峰. 但是,EP处理后CrN涂层的氧质量分数从6.32%增加至11.64%,且随着扫描速率的增加逐渐下降至8.24%. 由此说明,电化学极化生成了少量的非晶氧化物. 这些非晶氧化物密封了CrN涂层孔隙,使孔隙率从CrN0涂层的16.79%降至CrN15涂层的10.83%,这也使CrN涂层的硬度最多提高了21.2%. 经过EP处理后,CrN涂层的耐磨性均获得增强,其中CrN25涂层因高硬度、弱氧化磨损以及较好的塑性变形能力,表现出最低的磨损率,相对CrN0涂层降低了46.0%.

     

    Abstract: In order to seal the void defects in CrN coatings so as to improve its mechanical and tribological properties, the electrochemical linear polarization (EP) treatments at different scanning rates were applied on CrN coatings. The effects of scanning rate on the microstructure, mechanical and tribological properties of the CrN coatings were investigated. The results showed that the CrN coatings still presented a stable crystal structure comprising of CrN(111) after EP treatment. No diffraction peaks of chromium oxide were found in the X-ray diffractograms patterns (XRD). However, the oxygen content of CrN coatings increased from 6.32% to 11.64%, and decreased gradually to 8.24% with the increasing of the scanning rate. It proved that only a small amount of amorphous chromium oxides was generated. These chromium oxides sealed the coating pores and decreased the porosity of the coating from 16.79% to 10.83% as a result, which increased the hardness by the degree of 21.2%. Meantime, the wear resistance of CrN coatings was all enhanced after EP treatment. Among them, the CrN25 coating showed the lowest wear rate, which was reduced by 46.0% relative to the CrN0 coating due to its high hardness, weak oxidative wear, and better plastic deformation capability.

     

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