ISSN   1004-0595

CN  62-1224/O4

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Inconel 718合金激光熔覆Ni60/SiC复合涂层摩擦学及抗氧化性能

Tribological Properties and Oxidation Resistance of Laser Cladded Ni60/SiC Composite Coatings on Inconel 718 Alloy

  • 摘要: 为了提高Inconel 718合金在高温高压和强氧化等恶劣工况下的服役性能,采用激光熔覆在其表面上制备了掺杂不同SiC质量分数的Ni60-SiC复合涂层:Ni60-10% SiC (C1)、Ni60-20% SiC (C2)和Ni60-30% SiC (C3). 利用X射线衍射仪 (XRD)、扫描电子显微镜 (SEM)和能量色散仪 (EDS)等表征方法和高温摩擦磨损试验等性能测试方法,对涂层的物相、显微组织、显微硬度和摩擦学性能进行了系统分析,并深入探讨了其在室温及600 ℃下的磨损机理和800 ℃下的抗氧化性能. 结果表明:Ni60-SiC复合涂层的主要物相为(Fe, Ni)、CrNix、Ni3Si和Cr23C6;由于固溶强化、细晶强化以及弥散分布在涂层内部的硬质相,涂层的显微硬度为基材的2.6~3.1倍;室温和600 ℃下,C2涂层的减摩性和耐磨性均表现最佳,平均摩擦系数分别提高了20.44%和46.62%,磨损率分别降低了75.12%和63.70%;随着SiC含量的增加,犁削效应减弱和脆性脱黏出现导致平均摩擦系数先降低后上升;此外,所有涂层的抗氧化性能均优于基材,其中C3涂层表现出最优异的抗氧化性能.

     

    Abstract:
    In this study, in order to improve the service performance of Inconel 718 alloy under severe working conditions such as high temperature and high pressure and strong oxidation, three hybrid powder systems doped with different SiC mass fractions were prepared by laser melting coating, including Ni60-10% SiC (C1), Ni60-20% SiC (C2) and Ni60-30% SiC (C3). The microstructure and evolution of the coatings were analyzed in depth using testing and analysis techniques such as X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. The focus of this paper was on the tribological properties and oxidation resistance of the coating surfaces. The average microhardness was tested using Vickers hardness tester. Wear tests were carried out at room and elevated temperatures using a friction and wear tester in a ball-and-disc spinning configuration, and the wear profiles of the samples were measured using a probe-type surface profiler to examine the friction and wear characteristics. The frictional wear processes of three coatings were investigated. In addition, the wear processes and behavioral mechanisms of the surface coatings were further investigated by characterizing the work hardening and morphology of the damaged surfaces. Finally, the oxidative weight gain of the samples was tested using a single-temperature zone tube furnace to investigate the antioxidant properties of the coatings.
    The results showed that the main phases of Ni60-SiC composite coatings were (Fe, Ni), CrNix, Ni3Si and Cr23C6. The microhardness of the coatings was 2.6~3.1 times that of the substrate due to solid solution strengthening, fine grain strengthening and hard phases diffusely distributed within the coatings, with the highest microhardness of 749.5HV0.5 for the C2 coating. The C2 coating showed the best performance in terms of friction reduction and wear resistance at both room temperature and 600 ℃, with the friction reduction (average coefficient of friction) increased by 20.44% and 46.62% and the wear rate reduced by 75.12% and 63.70%, respectively. Under high temperature conditions, the oxide film generated on the surface of the coating played a lubricating role, which made the friction coefficient at high temperature lower than that at room temperature. The secondary reinforcement of hard phases, such as Ni3Si led to the wear rate of the composite coatings to be significantly lower than that of the substrate, among which the C2 coating had the optimal abrasion resistance at room temperature and 600 ℃, with the wear rate of 3.07×10−5 and 10.31×10−5 mm3/(N∙m), respectively. With the increase of SiC content, the weakening of the plowing effect and the appearance of brittle debonding led to a decrease and then an increase in the average friction coefficient. In addition, the oxidation resistance of all the coatings was better than that of the substrate, with the best oxidation resistance of the C3 coating with an oxidation rate of 5.32 mg2/(cm4∙h), which was mainly due to the synergistic effect of the Cr2O3 dense oxides and the liquid phase that could be formed to reduce the pore space after the melting of SiO2.

     

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