ISSN   1004-0595

CN  62-1224/O4

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热带海洋盐雾气氛自润滑耐磨防腐涂层技术研究新进展

Self-Lubricating and Wear-Resistant and Anti-Corrosive Multi-Functional Coating Technologies Applied in Tropical Marine Atmosphere

  • 摘要: 随着“南海海洋纵深开发”和“深海深地深空”国家战略持续推进,热带海洋气氛下的磨损与腐蚀耦合损伤成为海洋装备的关键技术瓶颈. 本文中通过对比我国四大海域(渤海、黄海、东海及南海)海洋多场作用因素及装备苛刻服役环境,重点指出了热带海洋(南海海域)工程装备运动传动系统/部件所面临的“摩擦-磨损-腐蚀”共性技术难题;讨论分析模拟海洋腐蚀介质与实海环境下DLC薄膜、陶瓷涂层、轻合金微弧氧化涂层、MoS2基粘结涂层(软质)和功能一体化高分子合金(软质)等自润滑涂层的摩擦磨损行为及其损伤失效特点;从界面协同与功能匹配角度提出了热带海洋动态自润滑耐磨防腐的科学问题及研究新思路,寄望提升我国在热带海洋高技术装备关键传动部件/系统自润滑防腐方面的技术水平.

     

    Abstract: With the advancement of "South China Sea Deep Development" national strategies, the level of independent research and development in the fields of marine high-tech equipment such as offshore drilling platforms, wind/nuclear power and ships has been significantly improved. Currently, the coupled damage of wear and corrosion on the key transmission systems/moving parts of high-tech equipment, running in the tropical marine atmosphere has become a common technical problem. This paper investigated and compared the annual temperature, relative humidity, salt spray concentration, salt deposition amount on the solid surface, atmospheric Cl- concentration and solar radiation intensity of the four major sea areas of Bohai Sea, Yellow Sea, East China Sea and South China Sea (as thermal field and chemical field factors) and motion/transmission parts serving conditions (as force field factor). Since the temperature and humidity of the salt fog atmosphere in the three cold sea areas of the Bohai Sea, the Yellow Sea and the East China Sea are relatively low, and the duration and intensity of UV radiation throughout the year are significantly weaker than those in the South China Sea (hot sea), this paper focused on the key technical bottleneck of "friction-wear-corrosion" faced by transmission systems and moving parts of South China Sea engineering equipment, which were used in high temperature, high humidity, high salt and strong ultraviolet environment. The tribology behaviors and the damage failure characteristics of self-lubricating coating materials, such as DLC films, ceramic coatings, light alloy micro-arc oxidation coatings, MoS2-based adhesive coatings (soft), functional integrated polymer alloy (soft) in the vacuum/inert gas, humidity, aqueous media, salt water, salt spray and actual ocean environment were discussed. Furthermore, the research progress and design limitations of the "friction-corrosion" evaluation methods in liquid medium, neutral salt spray and real sea salt spray atmosphere were summarized. Based on the previous researching data in laboratory and verification testing results on the actual tropical marine equipment, a new research strategy for self-lubricating and wear-resistant and anti-corrosion technologies applied to tropical marine salt spray atmosphere was proposed, that was, fabricating series "hard-soft" self-lubricating and wear-resistant and anti-corrosion composite coating materials via focusing on the scientific problems of interface synergy and functional combination, and establishing a database of dynamic corrosion protection and maintenance guarantee coatings and materials for the whole sea area marine equipment through building a new online monitoring method of multi-field coupling friction and wear in tropical marine atmosphere. It was hoped that this paper can provide ideas for improving the technical level of self-lubricating and anti-corrosion properties for tropical marine high-tech equipment and their key transmission systems/moving parts.

     

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