ISSN   1004-0595

CN  62-1224/O4

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不同法向载荷下TiN涂层磨损寿命与失效机理研究

Coating Life and Failure Mechanism of TiN Coating under Sliding Wear Condition with Different Normal Loads

  • 摘要: 采用阴极弧等离子沉积技术在高速钢(HSS)和硬质合金钢(WC-Co)基体上制备TiN涂层,利用往复摩擦磨损试验机、轮廓仪、扫描电子显微镜和能谱仪等分析了不同法向载荷下TiN涂层的摩擦磨损特性和失效过程,建立了涂层磨损寿命图. 研究结果表明:TiN涂层/HSS试样摩擦系数随循环次数增加呈上升趋势;TiN涂层/WC-Co试样在30 N法向载荷下的摩擦系数随循环次数呈上升趋势,在60~120 N法向载荷下摩擦系数波动较大. 涂层试样的磨损深度随法向载荷与循环次数的增加而增加. TiN涂层/HSS试样在30 N法向载荷的主要失效形式是磨粒磨损、轻微黏着磨损和氧化磨损,在60~120 N法向载荷的主要失效形式是涂层断裂、磨粒磨损和剥层磨损. TiN涂层/WC-Co试样在30~50 N法向载荷下的主要失效形式是磨粒磨损,在60~120 N法向载荷下的主要失效形式是严重剥层. TiN涂层的磨损寿命图可以分为两部分:涂层工作区和涂层失效区. 接触应力越大,涂层磨损寿命越短. 基体材料抵抗变形的能力越强,涂层磨损寿命越长. TiN涂层/HSS基体具有良好的抵抗法向载荷的能力和较长的磨损寿命.

     

    Abstract: This work aimed to explore the characteristics of wear process and failure form of TiN coating under different normal loads, and to explore the coating life under sliding wear condition of coatings on two kinds of substrates (high-speed steel (HSS) and cemented carbide (WC-Co)), and then to guide the matching between the substrate and coating and the choice of coating for cutting tools based on the service load condition. Titanium nitride (TiN) coating was prepared on HSS and WC-Co substrates using the Cathodic Arc Plasma Deposition technology under the same deposition process and parameters. The chemical component of TiN coating, HSS substrate and WC-Co substrate were detected via the energy dispersive spectrometer. The surface morphologies and surface roughness of TiN coatings were observed using scanning electron microscopy and profile-meter. The friction coefficient during the wear process of two substrates and TiN coatings were measured using a reciprocating friction wear test machine. After reciprocating friction and wear tests, wear profiles and wear morphologies of coating samples were analyzed via profile-meter, scanning electron microscope and energy dispersive spectrometer. Furthermore, based on the comprehensive analysis of friction coefficient, wear profiles and wear surface morphologies, maps of TiN coating life under sliding wear condition on different substrates were constructed. The stable friction coefficient of the HSS substrate was between 0.7 and 0.8, while that of the WC-Co substrate was between 0.2 and 0.3. For the friction coefficient of coated samples, with the increase in the number of cycles, the friction coefficient of the TiN coating on HSS were comparable to the stable friction coefficients of the substrates. The friction coefficient of TiN coating on WC-Co was about 0.5. It was found from the depth of the wear profile increased with the increase in the normal loads and the number of cycles. Based on observation and analysis of wear morphologies of the wear scars. The main failure forms of TiN coatings on HSS were abrasive wear, mild adhesive wear and oxidation wear under 30 N. Under the normal load of 60~120 N, the main failure forms were fracture, delamination and wear. During the wear process, the HSS substrate material underwent plastic deformation, and the broken coating would be embedded in the substrate for protection of the substrate. After that, as the number of cycles increased, the coating embedded in the substrate would be completely removed. The failure form of cemented carbide TiN coating was abrasive wear under 30~50 N. Under the normal load of 60~120 N, the main failure form was severe delamination. The map of TiN coating life under sliding wear condition was divided into two parts: coating working area and coating failed area. The life of the TiN coating on both substrates decreased with the increase in the normal load. TiN coating on HSS had the best ability to resist normal loads among the tested samples. The life of TiN coating was affected by the contact pressure and the ability to resist deformation of substrate material. The larger contact pressure led to the shorter coating life. Under the similar contact pressure conditions, the stronger ability of substrate to resist the deformation, the longer the coating life was.

     

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