ISSN   1004-0595

CN  62-1224/O4

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ATP改性UHMWPE水润滑轴承材料的摩擦学特性研究

Tribological Properties of ATP-Modified UHMWPE Water-Lubricated Bearing Materials

  • 摘要: 超高分子量聚乙烯(UHMWPE)轴承材料在低速重载工况下常发生严重磨损,通过添加改性填料能够显著提升其摩擦学性能. 凹凸棒土(ATP)作为一种改性填料能够增强基体材料的机械性能进而改善其摩擦特性,但是ATP作为填料往往会因为团聚效应而降低材料的补强效果. 通过对ATP进行表面改性处理可克服团聚效应,实现ATP与基体间的均匀共混. 通过表面化学包覆改性法制备由硅烷偶联剂KH570改性处理的ATP与UHMWPE共混制成复合材料,并与纯UHMWPE材料作对照试验. 利用RTEC摩擦试验机研究复合材料在水润滑条件下摩擦系数随载荷和转速的变化,以及材料填充含量对复合材料在低速重载(v=0.55 m/s、Fz=55 N)工况下磨损性能的影响. 利用傅里叶变换红外光谱仪(FTIR)、X射线衍射仪(XRD)、差示扫描量热仪(DSC)与电子万能材料试验机分别对ATP改性效果、熔融结晶行为及复合材料的重要力学性能进行表征测试. 试验结束后,利用表面轮廓仪与激光共聚焦显微镜观察复合材料表面形貌并分析其磨损机理. 结果表明:硅烷偶联剂KH570对ATP的改性效果良好,填充改性ATP能提高材料的邵氏硬度,且材料的拉伸性能随填充含量的提高呈下降趋势;对比纯UHMWP材料,复合材料的摩擦系数更低,适量的ATP填充能改善材料磨损性能,减小体积磨损率;试验中改性ATP质量分数为1%的复合材料其摩擦学性能最优,在低速重载时的摩擦系数及体积磨损率与纯UHMWPE相比分别降低了52.45%和37.58%.

     

    Abstract: The ultra high molecular weight polyethylene (UHMWPE) bearing material often suffers severe wear under low speed and heavy load condition. The tribological properties of UHMWPE bearing material can be greatly improved by adding self-lubricating filler. Atapulgite (ATP), as a modified filler, can enhance the mechanical properties of the material and improve its frictional properties, but agglomeration effect limits its dispersion in the matrix material. The surface modification of ATP can achieve uniform blending between ATP and the matrix. ATP modified by silane coupling agent KH570 was prepared by surface chemical coating modification method. The composite material was blended with UHMWPE and compared with pure UHMWPE. Under the condition of water lubrication, the variation of friction coefficient of composites under different loading and rotating speed conditions and the influence of material filling content on the wear performance of composites under low speed and heavy load conditions (v=0.55 m/s, Fz=55 N) were studied. Fourier transform infrared spectrometer, X-ray diffraction, differential scanning calorimetry and electronic universal material testing machine were used to characterize ATP modification effect, melt crystallization behavior and mechanical properties of composites. At the end of the experiment, the wear surface morphology of the composites and their duals was observed by surface profilometer and confocal laser microscope, and the wear mechanism was analyzed. The results showed that the silane coupling agent KH570 had a good effect on ATP modification, and the Shore hardness of the material was increased by filling ATP modification, and the tensile property of the material decreased with the increase of filling content. Compared to the pure UHMWP material, the friction coefficient of the composites was lower. An appropriate amount of ATP filling can improve the wear surface morphology and reduce the volume wear rate. In the experiment, the modified ATP content of 1% material had the best tribological properties, and its friction coefficient and volume wear rate at low speed and heavy load were reduced by 52.45% and 37.58%, respectively, compared to pure UHMWPE.

     

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