ISSN   1004-0595

CN  62-1224/O4

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水介质中丁腈橡胶溶胀机理及其对磨粒磨损行为影响

Swelling Mechanism and its Effect on Abrasive Wear Behavior of Nitrile Rubber in Water Medium

  • 摘要: 研究首先对不同丙烯腈质量分数的丁腈橡胶(18%、26%和41%,即N18、N26和N41)进行浸泡试验分析基于溶胀时间的静态溶胀行为. 然后进一步对溶胀前后的丁腈橡胶样品进行圆型及角型磨粒单向滑动磨粒磨损试验. 为了揭示丁腈橡胶的溶胀机理及溶胀对不同粒型作用下磨粒磨损行为的影响,对试样进行质量、硬度、交联链比重(NMR)和表面形貌(SEM)测试. 结果表明:丁腈橡胶溶胀度随时间的增加而增加,并于240 h后趋于平衡,溶胀影响下老化的主要原因为交联链破坏和物质溶解.丁腈橡胶硬度随溶胀时间的增加而降低. 溶胀后摩擦系数和磨损量增加,同粒径下磨粒磨损程度角型大于圆型,角型磨损受溶胀影响程度更大,其最大溶胀后磨损增量为圆型磨粒的1.56倍. 圆型和角型磨粒分别以滚动和滑动的方式进入摩擦副,形成压入坑和嵌入坑两种不同的表面形貌,溶胀后橡胶组织疏松软化导致表面凹坑加深. 丁腈橡胶溶胀及其对磨粒磨损的影响程度随丙烯腈含量的增加而减小.

     

    Abstract: In this study, time-based static swelling behavior was first investigated via immersion experiments of nitrile rubber with different acrylonitrile weight percentages (18%, 26% and 41%, i.e. N18, N26, and N41) respectively. Then the unidirectional sliding abrasive wear tests with different particle shapes of the NBR samples before and after swelling tests were further conducted. In order to reveal the swelling mechanisms and its effect on the abrasive wear, the weighting method, hardness tests, nuclear magnetic resonance and scanning electron microscopy were conducted and analyzed accordingly. The results showed that the swelling degree increased with the immersion time and the main influence on aging was crosslink chain destruction and substance dissolution, which led to the decrease of the nitrile rubber mass and the formation of the swelling layer. The nitrile rubber hardness decreased with the increasing swelling time. The friction coefficient and abrasion increased after swelling and the wear degree of the sharp type abrasive particle were higher than the smooth type under the same particle size. The sharp type abrasive wear can be more affected by swelling, and the maximum wear increase was 1.56 times of the smooth type after swelling. During the wear process under smooth type abrasive particle, the abrasive particles entered the friction pair mainly in rolling, which led to the pit-like press indentation. While under the sharp type abrasive wear process, the main entry form was sliding, which led to the sharp embedded indentation instead. Since the sharp type abrasive particle was not conducive to the formation of the lubricating film, a large amount of abrasive debris remained on the worn surface. The loosened and softened rubber tissue after swelling caused the deeper indentation and the ridge pattern formation. The acrylonitrile content effect degree of the swollen abrasive wear of the smooth type was larger than the sharp type, which had the greater wear variation multiples among the three different acrylonitrile content nitrile rubber. In general, the swelling degree and its effect on the abrasive wear behavior of the nitrile rubber under water conditions decreased with the increase of the acrylonitrile content.

     

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