ISSN   1004-0595

CN  62-1224/O4

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激光织构化固液复合涂层的仿生制备及其润滑减摩性能研究

Biomimetic Fabrication and Self-Lubricating Tribological Performance of Laser-Textured Solid-Liquid Composite Coatings

  • 摘要: 针对限量供油条件下润滑膜稳定性差和供给不足的问题,本研究中提出了1种仿生结构设计与磁控润滑协同增效的固液复合涂层新策略. 通过皮秒激光在镁合金表面织构仿生猪笼草月牙储油结构和鸢尾草楔形定向输运结构,结合喷涂二硫化钼(MoS2)固体润滑涂层与磁流体(MFs)润滑剂,构建了具有自供油与磁场调控功能的多尺度复合涂层(L-Mg@SMP/MoS2@MFs). 摩擦学测试表明:在200 r/min转速与5 N载荷下,复合涂层的摩擦系数较基材降低90% (0.057),磨损质量减少47%;引入350 mPa·s磁流体后,涂层寿命提升200%. 机理分析表明,月牙结构通过储油与压力梯度驱动润滑剂循环补给,楔形结构借助拉普拉斯力(24 μm/s)实现润滑剂定向输运,而在100 mT的磁场下,通过调控Fe3O4纳米颗粒(粒径约50 nm)的定向排列增强油膜稳定性(离心保持率>85%). 本研究内容为限量供油场景下的长效减摩设计提供了仿生-磁控协同新思路.

     

    Abstract: To address the problems of poor lubrication film stability and insufficient lubricant supply under limited-oil conditions, this study proposed a novel strategy of biomimetic design combined with magnetically controlled lubrication for synergistic enhancement in solid-liquid composite coatings. By employing picosecond laser etching on the surface of magnesium alloy, biomimetic Nepenthes-inspired crescent-shaped oil storage structures and iris-inspired wedge-shaped directional transport structures were fabricated. These were integrated with a sprayed molybdenum disulfide (MoS2) solid lubricant coating and a magnetorheological fluid (MFS) lubricant to construct a self-lubricating, magnetically tunable, multi-scale composite coating (L-Mg@SMP/MoS2@MFS). Tribological tests showed that under a rotation speed of 200 r/min and a load of 5 N, the composite coating reduced the friction coefficient by 90% (down to 0.057) compared to the substrate, and wear mass loss decreased by 47%. With the introduction of a 350 mPa·s MFS, the coating's lifespan increased by 200%. Mechanism analysis revealed that the crescent-shaped structures enabled lubricant recirculation via oil storage and pressure gradient-driven replenishment, while the wedge-shaped structures promoted directional lubricant transport through Laplace forces (24 μm/s). Magnetic field regulation further enhanced oil film stability through the aligned arrangement of Fe3O4 nanoparticles (average size about 50 nm), achieving a centrifugal retention rate of over 85%. This study offered a new biomimetic-magnetic synergistic approach for long-lasting friction reduction design under limited-oil lubrication scenarios.

     

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